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烟气颗粒物在线监测零点校准技术研究

Research on zero point calibration technology for online monitoring of flue gas particles

  • 摘要: 为解决烟气颗粒物浓度在线监测系统中因零点漂移导致的测量准确度降低问题,设计了一种基于激光散射法的烟气颗粒物质量浓度监测的零点自动校准系统。结合统计学中的概率理论,分析了零点漂移对测量准确度的影响过程,并通过实验室与现场实验对系统性能进行验证。试验结果表明:颗粒物质量浓度越低,零点漂移引起的测量误差越大,当烟气颗粒物排放浓度小于10 mg/m3时,零点漂移成为主要误差来源;零点漂移表现出波动上漂和波动下漂的特征,最大漂移量可达初始值的2.02倍;采用零点自动校准技术后,烟气颗粒物质量浓度在线监测系统在现场比对测试中的95%置信区间半宽达到6.3%,即95%的测量值相对误差小于6.3%。

     

    Abstract: In order to solve the problem of reduced measurement accuracy caused by zero drift in the online monitoring system for flue gas particles concentration, a zero point automatic calibration system for monitoring the mass concentration of flue gas particles based on laser scattering method was designed. Combining the probability theory in statistics, the influence process of zero drift on measurement accuracy was analyzed, and the system performance was verified through laboratory and on-site experiments. The test results show that the lower the mass concentration of particles, the greater the measurement error caused by zero drift. When the emission concentration of flue gas particles is less than 10 mg / m3, zero drift becomes the main source of error. Zero drift exhibits the characteristics of fluctuating up and down, with a maximum drift value of 2. 02 times the initial value. The online monitoring system for mass concentration of gas particles using zero point automatic calibration achieves a 95% confidence interval half width of 6. 3% in on-site comparative testing. That is, the relative error of 95% of the measured values is less than 6.3%

     

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